Problem 1:
Calculate the kinetic effect for breaking R-H/R-T and R-D/R-T bonds. Take for carbon-hydrogen bond stretching frequency as 2900 cm−1. Assume T=300 K.
Problem 2:
Calculate the kinetic effect for breaking 12C − H versus 13C − H bonds, assuming a 12C − H stretching frequency of 2900 cm−1 . Assume T=300 K.
Solution 1:
Kinetic isotope effect for breaking R-H/R-T is given by,
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