**Problem 1:**

Calculate the kinetic effect for breaking R-H/R-T and R-D/R-T bonds. Take for carbon-hydrogen bond stretching frequency as 2900 cm^{−1}. Assume T=300 K.

**Problem 2:**

Calculate the kinetic effect for breaking ^{12}C − H versus ^{13}C − H bonds, assuming a ^{12}C − H stretching frequency of 2900 cm^{−1} . Assume T=300 K.

**Solution 1:**

Kinetic isotope effect for breaking R-H/R-T is given by,

…………………………………………………………………………………………………………………………………………………………………………………………………………………..

This solution is available for sale in pdf format for just 21.99 USD. Please fill in the following form and submit your order to **Detailed Solution**.

### Like this:

Like Loading...