Kinetic Effect for Breaking the Bonds

Problem 1:
Calculate the kinetic effect for breaking R-H/R-T and R-D/R-T bonds. Take for carbon-hydrogen bond stretching frequency as 2900 cm⁻¹. Assume T=300 K.

Problem 2:
Calculate the kinetic effect for breaking ¹²C − H versus ¹³C − H bonds, assuming a ¹²C − H stretching frequency of 2900 cm⁻¹ . Assume T=300 K.

Solution 1:
Kinetic isotope effect for breaking R-H/R-T is given by,

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